MAGNETIC ACTIVATION OF ION EXCHANGE PROCESS DURING DEMINERALISATION OF NATURAL WATERS

PDF(UKRAINIAN)

 

Kovtun David

National University of Civil Protection of Ukraine, Cherkasy, Ukraine

https://orcid.org/0009-0001-8911-4148

 

Dushkin Stanislav

Kharkiv National Automobile and Highway University, Kharkiv, Ukraine

https://orcid.org/0000-0002-9345-9632

 

DOI: 10.52363/2522-1892.2024.2.8

 

Keywords: water demineralization, ion exchange, magnetic activation, cationite, water treatment

 

Abstract

The process of demineralizing natural water involves removing heavy metal ions and other pollutants from it. Given the current environmental trends, including environmental degradation and water pollution, there is a need to improve the efficiency of water treatment methods while minimizing the environmental impact. Reagent demineralization methods are widely used in water treatment systems, but they are often accompanied by high economic and resource costs, as well as additional pollution. A promising area is the combined use of reagent treatment with other demineralization methods, in particular the ion exchange method, which has been actively developing in recent years. This method is based on the stoichiometric exchange of ions between ion exchange materials and water.

The article deals with the issue of magnetic activation of the ion exchange process in the demineralization of natural waters. The analysis of existing water treatment systems using the method of ion exchange is carried out and the parameters that need to be improved are determined. A mathematical model for evaluating the efficiency of magnetic activation of cationite KU-2x8 is proposed. The analysis confirms the relevance of research in the field of intensification of ion exchange processes to improve environmental safety and efficiency of water demineralization. The results demonstrate the influence of such parameters as the initial water hardness and magnetic field intensity on the total exchange capacity of the cationite.

 

References

  1. Soroka, M., Bailiuk, Y., Daniliak, A., Zelenko, Y., & Tarasova, L. (2022). Analiz ta ekolohichna otsinka rezultativ monitorynhu pryrodnykh pytnykh vod u malykh hromadakh Ukrainy: Zvit pro naukovo-doslidnu robotu [Analysis and ecological assessment of the results of monitoring natural drinking water in small communities of Ukraine]. DOI: 10.13140/RG.2.2.11787.67360. [in Ukrainian]

  2. Thiripelu, P., Manjunathan, J., Revathi, M., & Ramasamy, P. (2024). Removal of hexavalent chromium from electroplating wastewater by ion-exchange in presence of Ni(II) and Zn(II) ions. Journal of Water Process Engineering, 58, 104815. DOI: 10.1016/j.jwpe.2024.104815.

  3. Jasim, A. Q., & Ajjam, S. K. (2024). Removal of heavy metal ions from wastewater using ion exchange resin in a batch process with kinetic isotherms. South African Journal of Chemical Engineering. DOI: 10.1016/j.sajce.2024.04.002.

  4. Bekchanov, D., Mukhamediev, M., Juraev, M., & Alosmanov, R. (2024). Removal of Ca(II) and Mg(II) ions from solutions to sulfonic cation exchanger based on plasticized polyvinylchloride. Phosphorus, Sulfur, and Silicon and the Related Elements, 199(3), 201–209. DOI: 10.1080/10426507.2024.2315530.

  5. Almoukayed, A. A., & Barhoum, R. (2023). Chemical modification of keratin using Schiff bases to prepare cation exchangers and study their adsorption activity. Heliyon, 9(5), e15567. DOI: 10.1016/j.heliyon.2023.e15567.

  6. Zhang, H., Carrillo, F., López-Mesas, M., & Palet, C. (2018). Valorization of keratin biofibers for removing heavy metals from aqueous solutions. Textile Research Journal, 89(7), 1153–1165. DOI: 10.1177/0040517518764008.

  7. Kovtun, D., & Dushkin, S. (2024). Mahnitna modyfikatsiia ionoobminnykh protsesiv [Magnetic modification of ion exchange processes]. Technogenic and Ecological Safety, 15(1/2024), 75–79. DOI: 10.52363/2522-1892.2024.1.8. [in Ukrainian]

  8. Savchenko, V., Sinyavsky, O., & Bunko, V. (2019). Vplyv mahnitnoho polia na vodu [Influence of magnetic field on water]. Energy and Automation, 2019(1), 6–15. DOI: 10.31548/energiya2019.01.006. [in Ukrainian]

  9. Jawad, S. I., Karkush, M., & Kaliakin, V. N. (2023). Alteration of physicochemical properties of tap water passing through different intensities of magnetic field. Journal of the Mechanical Behavior of Materials, 32(1). DOI: 10.1515/jmbm-2022-0246.

  10. Bozhedai, P., & Tyutko, S. M. (2021). Suchasni metody obrobky vody [Modern methods of water treatment]. Statti ta tezy Fakhovy College. Fakhovy College of National Pharmaceutical University. https://college.nuph.edu.ua/wp-content/uploads/2021/04/%D0%91%D0%BE%D0%B6%D0%B5%D0%B4%D0%B0%D0%B9-%D0%A2%D1%8E%D1%82%D1%8C%D0%BA%
    D0%BE.pdf. [in Ukrainian]

  11. Dushkin, S., & Shevchenko, T. (2020). Applying a modified aluminium sulfate solution in the processes of drinking water preparation. Eastern European Journal of Enterprise Technologies, 4(10-106), 26–36. DOI: 10.15587/1729-4061.2020.210096.

  12. Mascolo, M. C. (2021). Effect of magnetic field on calcium carbonate precipitated in natural waters with prevalent temporary hardness. Journal of Water Process Engineering, 41, 102087. DOI: 10.1016/j.jwpe.2021.102087.

  13. Sajjadi Shourije, S. M. J., Dehghan, P., Bahrololoom, M. E., Cobley, A. J., Vitry, V., Azar, G. T. P., Kamyab, H., & Mesbah, M. (2023). Using fish scales as a new biosorbent for adsorption of nickel and copper ions from wastewater and investigating the effects of electric and magnetic fields on the adsorption process. Chemosphere, 322, 137829. DOI: 10.1016/j.chemosphere.2023.137829.

  14. Ahmaruzzaman, M. (2011). Industrial wastes as low-cost potential adsorbents for the treatment of wastewater laden with heavy metals. Advances in Colloid and Interface Science, 166(1-2), 36-59. DOI: 10.1016/j.cis.2011.04.005.

  15. Dushkin, S. (2023). Study of the process of activation of aluminum sulfate coagulant solutions during filtration on rapid filters. International Journal of Chemistry, Mathematics and Physics, 7(6), 0106. DOI: 10.22161/ijcmp.7.6.1.

  16. Dushkin, S., & Kovtun, D. (2024). Intensyfikatsiia protsesiv ionnoho obminu v systemakh vodopidhotovky [Intensification of ion exchange processes in water supply systems]. Problems of Water Supply, Sewerage and Hydraulic, 46, 4–13. DOI: 10.32347/2524-0021.2024.46.4-13. [in Ukrainian]

  17. Ho, K. T., Konovets, I. M., Terletskaya, A. V., Milyukin, M. V., Lyashenko, A. V., Shitikova, L. I., Shevchuk, L. I., Afanasyev, S. A., Krot, Y. G., Zorina-Sakharova, K. Ye., Goncharuk, V. V., Skrynnyk, M. M., Cashman, M. A., & Burgess, R. M. (2020). Contaminants, mutagenicity and toxicity in the surface waters of Kyiv, Ukraine. Marine Pollution Bulletin, 155, 111153. DOI: 10.1016/j.marpolbul.2020.111153.

  18. Shukla, S., Mbingwa, G., Khanna, S., Dalal, J., Sankhyan, D., Malik, A., & Badhwar, N. (2023). Environment and health hazards due to military metal pollution: A review. Environmental Nanotechnology, Monitoring & Management, 100857. DOI: 10.1016/j.enmm.2023.100857.

  19. Lazăr, N.-N., Simionov, I.-A., Petrea, Ș.-M., Iticescu, C., Georgescu, P.-L., Dima, F., & Antache, A. (2024). The influence of climate changes on heavy metals accumulation in Alosa immaculata from the Danube River Basin. Marine Pollution Bulletin, 200, 116145. DOI: 10.1016/j.marpolbul.2024.116145.

  20. Choudhury, T. R., Ferdous, J., Haque, Md. M., Rahman, Md. M., Quraishi, S. B., & Rahman, M. S. (2022). Assessment of heavy metals and radionuclides in groundwater and associated human health risk appraisal in the vicinity of Rooppur nuclear power plant, Bangladesh. Journal of Contaminant Hydrology, 251, 104072. DOI: 10.1016/j.jconhyd.2022.104072.